The very long link below is to the timetable for the TransPerth Fremantle line that shows when the trains are in each area. The link at the bottom shows the crime rate by suburb which is important if you get off work at such a late hour. Between the two, you should be able to find an acceptable location.
Timetable:
http://www.transperth.wa.gov.au/TimetablesMaps/www.transperth.wa.gov.au/TimeTables/tabid/235/Default.aspx?UserInputServNum=&Direction=outbound&UserInputServiceProvider=&FromLoc=&SchoolBusVehicleType=false&Date=31%2f01%2f2013&find%2btimetables.x=&find%2btimetables.y=&TrainVehicleType=true&FerryVehicleType=false&BusVehicleType=false
Crime Rates:
http://www.homeinperth.blogspot.com/2012/05/how-dodgy-is-your-perth-suburb-council.html